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Kulkarni, Atish & Kuman, Akshai & Goldman, Alan S. & Celik, Fuat E. (2016). Selectivity for dimers in pentene oligomerization over acid zeolites. Catalysis Communications, 75, , 98-102. Retrieved from https://doi.org/doi:10.7282/T3542QJN

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Selectivity for dimers in pentene oligomerization over acid zeolites (2016)
Atish Kulkarni, Akshai Kuman, Alan S. Goldman, Fuat E. Celik
Catalysis Communications 75, : 98-102.
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AbstractThe reactions of 1-pentene over acid zeolites were investigated in the liquid phase at 473 K. The primary reactions were isomerization, dimerization, and subsequent cracking of dimers. Zeolites consisting of only 10-membered (MFI) or 12-membered rings (FAU, BEA) behaved similarly, with dimerization and subsequent cracking products observed. Zeolites possessing 8-membered ring pores (MOR, FER) showed very different selectivity from each other and from other zeolites. MOR showed almost complete conversion of C10 olefins, such that hexene and butene from cracking were the dominant products. FER showed high activity and selectivity for dimerization, with very small amounts of cracking products observed.
Persistent URLhttps://doi.org/doi:10.7282/T3542QJN
Subjects1-pentene, Oligomerization, Oligomers, Dimerization, Dimers, Zeolites, Ferrierite, Cracking process
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